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I was surprised to learn that the freezing point of pure acetic acid is 16 deg. Centigrade. https://www.sciencedirect.com/science/article/abs/pii/S016776750080041X#:~:text=properties of acetic acid.,point is %2B16.6 °C.  Since vinegar is typically 4-8% acetic acid in water, the water actually lowers the freezing point.

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