Make sure the piece stays flat, don't accidentally lift the left side up higher than the right side where you are stitching. Causes the needle holes to be slanted so the back stitch is skewed compared to the top side. Also watch how it is feeding. If the feet don't sit squarely on the throat plate, it will drag the item to one side of the other.
If you are using contact cement properly, it should not be able to skew the top and bottom pieces. Double sided tape is generally not as secure as contact cement.
When sewing close to the edge like this, the leather is trapped between the outside foot and the throat plate on the left, but only trapped by the feet and the feed dog on the right side, so will tend to drive you off sewing in a straight line.
Not sure if this is what you having trouble with, but hope it helps. You'll probably get some better answers from @Wizcrafts or others yet.
Tom